膜
渗透汽化
海水淡化
聚酰胺
化学工程
薄膜复合膜
反渗透
石墨烯
水溶液
氧化物
盐(化学)
材料科学
化学
色谱法
高分子化学
渗透
有机化学
生物化学
工程类
作者
Elnaz Halakoo,Xinbin Feng
标识
DOI:10.1016/j.seppur.2019.116077
摘要
This study reports on surface modification of thin-film-composite (TFC) polyamide membranes for desalination of high-salinity water via pervaporation. The membrane modification involves surface treatment of the polyamide membrane with chlorine, followed by layer-by-layer (LbL) deposition of positively charged polyethyleneimine (PEI) and negatively charged graphene oxide (GO). It was shown that the controlled membrane chlorination significantly increased water permeability and incorporating PEI and GO to the chlorine-treated polyamide membrane improved the salt rejection. The pure water flux through the PEI/GO LbL membrane was two times higher than that through the original membrane. The PEI/GO LbL membrane was tested for desalination of aqueous solutions containing NaCl, Na2SO4, MgSO4 andMgCl2 salts, and a water flux as high as 8 kg/m2h with a high salt rejection (>99.9%) was obtained for all the tested salts at various temperatures and feed concentrations.
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