Significant Enhancement of Gaseous Elemental Mercury Recovery from Coal-Fired Flue Gas by Phosphomolybdic Acid Grafting on Sulfurated γ-Fe2O3: Performance and Mechanism

The existing technologies to control Hg emissions from coal-fired power plants can be improved to achieve the centralized control of Hg⁰ emissions, which continue to pose a risk of Hg exposure to human populations. In this work, MoS_x@γ-Fe₂O₃, formed by the sulfuration of phosphomolybdic acid (HPMo)-grafted γ-Fe₂O₃, was developed as a magnetic and regenerable sorbent to recover gaseous Hg⁰ from coal-fired flue gas as a cobenefit to the use of wet electrostatic precipitators. The thermal stability of γ-Fe₂O₃ was notably enhanced by HPMo grafting; thus, the magnetization of MoS_x@γ-Fe₂O₃ hardly decreased during the application. The kinetic analysis indicates that the chemical adsorption of gaseous Hg⁰ was mainly dependent on the amounts of surface S₂^2- and surface adsorption sites. Although the amount of S₂^2- on sulfurated γ-Fe₂O₃ decreased after HPMo grafting, the amount of surface adsorption sites significantly increased due to the formation of a layered MoS_x structure on the surface. Therefore, the ability of sulfurated γ-Fe₂O₃ to capture Hg⁰ was improved considerably after HPMo grafting. Furthermore, low concentrations of gaseous Hg⁰ in coal-fired flue gas can be gradually enriched by at least 1000 times by MoS_x@γ-Fe₂O₃, which facilitates the recovery and centralized control of gaseous Hg⁰ in flue gas.