Simultaneous absorption and hydrogenation of CO2 from flue gas by KBH4 catalyzed by nickel nanoparticles supported on TiO2

烟气 催化作用 格式化 甲烷 二氧化碳 材料科学 化学工程 无机化学 碳纤维 化学 有机化学 冶金 复合数 工程类 复合材料
作者
Yi Zhao,Tianhao Wang,Yongbin Wang,Runlong Hao,Weitian Hui
出处
期刊:Chemical Engineering Journal [Elsevier BV]
卷期号:380: 122523-122523 被引量:7
标识
DOI:10.1016/j.cej.2019.122523
摘要

Considering that the carbon dioxide (CO2) emissions resulting from the combustion of fossil fuels significantly aggravate the global greenhouse effect and frequently lead to extreme environmental problems, it was proposed in this work to carry out the simultaneous capture and resource utilization of CO2 from flue gas by using a low-energy method. Importantly, nickel nanoparticles supported on titanium dioxide (Ni [email protected]2) was prepared to catalyze potassium borohydride (KBH4) to be transformed into BH4-n(OH)n− (n = 0–3) species with strong hydride donation capacity, which hydrogenated CO2 to formate under atmospheric pressure and mild temperature. The optimum experimental conditions for the catalytic hydrogenation of CO2 were determined by investigating the effects of various factors on the CO2 conversion: the Ni [email protected]2 dosage was 1 g·L−1, KBH4 concentration was 0.2 mol·L−1, solution pH was 9.5, reaction temperature was 60 °C and flow velocity of flue gas was 0.5 L·min−1. The average CO2 conversion efficiency was achieved as 51.2% under the optimal conditions. Based on a series of catalyst characterizations, product analyses and related literatures, the catalytic hydrogenation reaction mechanism for the conversion of CO2 to formate was analyzed. This work can provide reference for developing the processes for CO2 emission reduction combined with resource utilization.
最长约 10秒,即可获得该文献文件

科研通智能强力驱动
Strongly Powered by AbleSci AI
科研通是完全免费的文献互助平台,具备全网最快的应助速度,最高的求助完成率。 对每一个文献求助,科研通都将尽心尽力,给求助人一个满意的交代。
实时播报
XXHH完成签到,获得积分10
1秒前
yj91完成签到,获得积分10
4秒前
小明关注了科研通微信公众号
5秒前
稳重向南完成签到,获得积分10
7秒前
12秒前
吴建文完成签到 ,获得积分10
13秒前
拾石子完成签到 ,获得积分10
18秒前
zz完成签到 ,获得积分10
21秒前
23秒前
汉堡包应助stws采纳,获得10
23秒前
关中人完成签到,获得积分10
24秒前
adam完成签到,获得积分10
26秒前
FashionBoy应助科研通管家采纳,获得10
27秒前
27秒前
情怀应助科研通管家采纳,获得10
27秒前
NexusExplorer应助科研通管家采纳,获得10
27秒前
科研通AI5应助科研通管家采纳,获得10
27秒前
彭于晏应助科研通管家采纳,获得10
27秒前
Lucas应助科研通管家采纳,获得10
27秒前
27秒前
27秒前
shiyi完成签到,获得积分10
27秒前
燕子应助科研通管家采纳,获得100
27秒前
27秒前
28秒前
动漫大师发布了新的文献求助10
28秒前
stws完成签到,获得积分20
28秒前
左右脑完成签到,获得积分10
29秒前
Lucas应助Ztx采纳,获得10
30秒前
科研通AI5应助小小文采纳,获得30
32秒前
雨成完成签到 ,获得积分10
33秒前
shiyi发布了新的文献求助10
35秒前
jjj完成签到,获得积分10
35秒前
supertkeb应助骉骉采纳,获得10
36秒前
Jinnnnn完成签到 ,获得积分10
37秒前
Yqx完成签到,获得积分10
39秒前
zumrat关注了科研通微信公众号
40秒前
SYLH应助DrSong采纳,获得20
40秒前
gzslwddhjx完成签到,获得积分10
42秒前
48秒前
高分求助中
【此为提示信息,请勿应助】请按要求发布求助,避免被关 20000
Production Logging: Theoretical and Interpretive Elements 3000
CRC Handbook of Chemistry and Physics 104th edition 1000
Izeltabart tapatansine - AdisInsight 600
Introduction to Comparative Public Administration Administrative Systems and Reforms in Europe, Third Edition 3rd edition 500
Distinct Aggregation Behaviors and Rheological Responses of Two Terminally Functionalized Polyisoprenes with Different Quadruple Hydrogen Bonding Motifs 450
Individualized positive end-expiratory pressure in laparoscopic surgery: a randomized controlled trial 400
热门求助领域 (近24小时)
化学 材料科学 医学 生物 工程类 有机化学 物理 生物化学 纳米技术 计算机科学 化学工程 内科学 复合材料 物理化学 电极 遗传学 量子力学 基因 冶金 催化作用
热门帖子
关注 科研通微信公众号,转发送积分 3761774
求助须知:如何正确求助?哪些是违规求助? 3305540
关于积分的说明 10134658
捐赠科研通 3019564
什么是DOI,文献DOI怎么找? 1658226
邀请新用户注册赠送积分活动 791989
科研通“疑难数据库(出版商)”最低求助积分说明 754751