电解质
阻燃剂
材料科学
电极
电镀(地质)
阴极
金属
化学工程
阳极
金属锂
冶金
化学
地球物理学
地质学
工程类
物理化学
作者
Shuang‐Jie Tan,Junpei Yue,Xingliu Hu,Zhenxing Shen,Wenpeng Wang,Jinyi Li,Tong‐Tong Zuo,Hui Duan,Yao Xiao,Ya‐Xia Yin,Rui Wen,Yu‐Guo Guo
标识
DOI:10.1002/anie.201903466
摘要
Safety concerns are impeding the applications of lithium metal batteries. Flame-retardant electrolytes, such as organic phosphates electrolytes (OPEs), could intrinsically eliminate fire hazards and improve battery safety. However, OPEs show poor compatibility with Li metal though the exact reason has yet to be identified. Here, the lithium plating process in OPEs and Li/OPEs interface chemistry were investigated through ex situ and in situ techniques, and the cause for this incompatibility was revealed to be the highly resistive and inhomogeneous interfaces. Further, a nitriding interface strategy was proposed to ameliorate this issue and a Li metal anode with an improved Li cycling stability (300 h) and dendrite-free morphology is achieved. Meanwhile, the full batteries coupled with nickel-rich cathodes, such as LiNi0.8 Co0.1 Mn0.1 O2 , show excellent cycling stability and outstanding safety (passed the nail penetration test). This successful nitriding-interface strategy paves a new way to handle the incompatibility between electrode and electrolyte.
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