化学
催化作用
胺化
烯丙基重排
烯胺
胺气处理
分子间力
电化学
组合化学
有机化学
分子
电极
物理化学
作者
Zheng Tan,Xiang Fang,Kun Xu,Cheng‐Chu Zeng
出处
期刊:Organic Letters
[American Chemical Society]
日期:2022-07-19
卷期号:24 (29): 5345-5350
被引量:23
标识
DOI:10.1021/acs.orglett.2c01983
摘要
The organoselenium-catalyzed amination of alkenes is a promising way to construct functionalized amines. However, the use of chemical oxidants and the unavoidable formation of allylic amine or enamine are the two main limitations of these methodologies. Against this background, we herein report an electro-selenocatalytic regime for the hydroazolylation of alkenes with azoles under external oxidant-free conditions with low catalyst loadings. Moreover, this protocol enables the generation of amines without vinyl substituents.
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