多硫化物
硫黄
咪唑酯
锂硫电池
材料科学
氢氧化物
阴极
化学
锂(药物)
电池(电)
无机化学
化学工程
电解质
电化学
电极
冶金
功率(物理)
物理化学
内分泌学
工程类
物理
医学
量子力学
作者
Jing Li,Weilong Qiu,Xin Liu,Yongguang Zhang,Yan Zhao
标识
DOI:10.1002/celc.202101211
摘要
Abstract Lithium‐sulfur (Li−S) batteries have become a research focus for high‐energy‐density rechargeable batteries owing to the considerable theoretical energy density. However, the polysulfide shuttle and sluggish kinetics in lithium‐sulfur (Li−S) chemistry lead to low sulfur utilization, large polarization and rapid capacity decay, posing a fatal threat to the commercialization of Li−S batteries. Herein, we etched zeolitic imidazolate framework‐67 (ZIF‐67) with Ni 2+ to manufacture NiCo‐LDH, which is used as a sulfur host material for lithium‐sulfur (Li−S) batteries. Benefited from the closely packed nano‐clusters and the hollow structure, the NiCo‐LDH could not only inhibit the lithium polysulfides (LiPSs) diffusion but also accelerate the redox reactions. Owing to these properties, the corresponding Li−S batteries exhibit a superior capacity (1540 mAh g −1 at 0.1 C) and high rate performance (485 mAh g −1 at 5.0 C). This work shows a promising way for layered double hydroxide as cathodes for Li−S batteries.
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