硝基
烯丙基重排
化学
位阻效应
烯烃
光化学
激进的
衍生工具(金融)
药物化学
有机化学
催化作用
金融经济学
经济
作者
Joseph E. Babiarz,Glen T. Cunkle,Anthony D. DeBellis,David Eveland,Stephen D. Pastor,Sai P. Shum
摘要
The reaction of stable sterically hindered nitroxyl radicals with benzylic and allylic substrates was investigated. An allyloxyamine derivative was obtained by the reaction of 2 molar equiv of a nitroxyl radical with an unactivated alkene. Experimental and computational evidence is consistent with a low-energy pathway involving addition of the nitroxyl radical to the double bond followed by H-atom abstraction from the intermediate by another equivalent of nitroxyl radical.
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