光电流
检出限
兴奋剂
水溶液中的金属离子
材料科学
线性范围
离子
金属
电极
电化学
分析化学(期刊)
纳米技术
无机化学
光电子学
化学
冶金
物理化学
有机化学
色谱法
作者
Yihe Zhang,Hongmin Ma,Dan Wu,Rongxia Li,Xueping Wang,Yaoguang Wang,Wenjuan Zhu,Qin Wei,Bin Du
标识
DOI:10.1016/j.bios.2015.10.074
摘要
An efficient strategy for the sensitive detection of Cd(2+) and Cu(2+) on the same sensing platform was first developed based on the photocurrents generated from the electrodeposited Zn doped CdS (CdZnS) film. The enhancement of the photocurrents, which was directly obtained from the in situ electrodeposited CdZnS on ITO with the gradual addition of Cd(2+), was used an indicator for the content of Cd(2+) with theoretical and technical simplicity. Moreover, the electrodeposited CdZnS was further applied to sensing of Cu(2+) based on the interaction between Cu(2+) and S(2-) by immersing the hetero-structural film electrode into a Cu(2+)-containing sample for an appropriate time, leading to decrease the photocurrent of CdZnS. The decrease extent of photocurrent was depended on the concentration of Cu(2+) in the sample solution. Due to the sensitivity of the photoelectrochemical (PEC) sensor was enhanced obviously through the doping of Zn, the present electrodeposited PEC method demonstrated acceptable linear range of 10(-9)-10(-2)M and 10(-8)-10(-4)M, with low detection limit down to 0.35 nM and 3 nM for Cd(2+) and Cu(2+) respectively, which were lower than the Environmental Protection Agency (EPA) and World Health Organization (WHO) guidelines. The proposed CdZnS-based PEC strategy achieved two metal ions detection on the same sensing platform, which had positive and significant effect on solving the common problems, such as time-consuming, high cost, complex operation and high detection limit in the detection of metal ions. In addition, the proposed PEC device was further successfully applied to an assay of Cd(2+) and Cu(2+) in water sample.
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