TiO₂photocatalysis: progress from fundamentals to modification technology

AbstractHeterogeneous photocatalysis is a promising method among advanced oxidation processes, which can be used for degradation of various organic pollutants in water and air. In heterogeneous photocatalysis, illumination of an oxide semiconductor, usually the anatage form of titanium dioxide, by UV radiation produces photo-excited electrons () and positively charged holes (). In the aqueous phase, the illuminated surface is extensively regarded as a producer of hydroxyl radicals (). These hydroxyl radicals, holes, and conduction-band electrons can degrade organic pollutants directly or indirectly. However, the massive recombination of these photo-generated charge carriers and large band gap of limits its overall photocatalytic efficiency. These limitations can be overcome by changing surface properties of titania by adding suitable electron scavengers in the reaction medium or by modifying its electronic band structure through strategies like metal ion/nonmetal atom doping, narrow band-gap semiconductor...