Synergization of yield strength and ductility for a dilute Mg-Zn-Nd-Ca alloy through pinned twin boundary and Guinier–Preston zone

• A dilute quaternary Mg-0.6Zn-0.4Nd-0.2Ca (wt.%) was designed based on an overall consideration of stacking fault energy, solute atoms segregation energy and diffusion activation energy, to tailor the ductility and strength of magnesium via Guinier-Preston zone (G.P. zone) and pinned twin boundary. • Zn and Nd elements co-segregate at the twin boundary, while Ca element segregates alone, and fine precipitates of (Mg, Zn) 3 Nd and Mg 2 Ca with the size of 5∼20 nm underwent significant preferential precipitation at the twin boundary. • Compared with Ca atoms, Zn atoms tend to combine with Nd atoms more preferentially towards the stacking faults, thereby forming a high-density monolayer G.P. zone enriched with Zn and Nd atoms. • A good combination of yield strength and ductility was achieved in this dilute alloy with yield strength of 141 MPa and ultimate compression of 31.7 % at room temperature. Mg-Zn-RE alloys typically exhibit non-basal texture, weak dispersion hardening, and low yield strength. In this study, we designed a dilute quaternary Mg-0.6Zn-0.4Nd-0.2Ca (wt.%) alloy. Then, applied pre-strain and heat treatment to investigate the balance of yield strength and ductility via solute atom segregation at twin boundaries and nanophase modifications. The results indicated that Zn and Nd elements tend to co-segregate at the twin boundary, while Ca element segregates alone and presents a discontinuous distribution. Nanoscale precipitates of (Mg, Zn) 3 Nd and Mg 2 Ca with the size of 5∼20 nm underwent significant preferential precipitation at the twin boundary. Moreover, compared with Ca atoms, Zn atoms tend to combine with Nd atoms more preferentially towards the stacking faults, thereby forming a high-density monolayer Guinier-Preston (G.P.) zone. The segregation and precipitation of solute atoms at the twin boundary and the stacking faults increased the friction stress of twinning dislocations and lattice dislocations, thus improving the strength. Pinned twin boundaries facilitate the transition from basal 〈 a〉 slip to pyramidal 〈 c + a〉 slip due to the small geometrical compatibility factor ( m ′) value as well as the Schmid factor (SF) incompatibility. As a result, the pre-strained and heat-treated specimen's yield strength exhibits a 141 % increase relative to the initial state specimen, accompanied by a modest improvement in ductility. The mechanism of multi-element segregation and precipitation at twin boundaries, and G.P. zone formation was discussed in detail.