Selective hydrodeoxygenation of lignin to 4‐ethylcyclohexanol catalyzed by Cu–Ni/MgCrOx spinel

Abstract A novel approach is proposed for producing 4‐ethylcyclohexanol, a versatile petrochemical in the polymer industry, from the renewable lignin in the presence of Cu–Ni/MgCrO x spinel catalysts. Under the synergistic effect between the Ni 0 , Cu, + and the balanced acidic and basic properties of MgO and MgCr 2 O 4 , an exceptional yield of monomer (30.1 wt%) with 59.5% selectivity of 4‐ethylcyclohexanol (yield of 17.9 wt%) was achieved when the depolymerization of bamboo lignin was performed with Cu 6 Ni 20 /MgCr 0.5 O x (Cr:Mg = 0.5). Catalyst characterization illustrated that the formation of MgCr 2 O 4 spinel, which restrained the generation of NiMgO 2 solid solution and increased the concentration of Ni 0 species, along with the surface electron effect between Ni 0 and Cu + , contributes to this superior hydrodeoxygenation performance of lignin. Mechanistic investigation further demonstrated that the conversion of lignin to 4‐ethylcyclohexanol involves a tandem process of C β –O bonds cleavage, demethoxylation, and saturated hydrogenation. Therefore, this work provides new insights on lignin utilization.