Strengthening Liquid Crystal Elastomer Muscles.

ConspectusLiquid crystal elastomer fibers (LCEFs) are reversible artificial muscles capable of stimuli-responsive functions, making them promising competitors for ideal soft actuators. These remarkable actuation properties depend strongly on their mechanical properties, such as elastic modulus and breaking stress. It is necessary to strengthen the LCEF muscles to meet the demands of advanced applications. However, despite the significant progress in LCEFs, there is currently no such Account systematically summarizing and analyzing the strategies adopted for enhancing their mechanical and actuation properties. The intuitive variations among the different enhancement strategies further call for investigations into how to choose the most suitable ones based on specific situations. In this Account, for the first time, we systematically summarize existing approaches to strengthening LCEF-based artificial muscles, contributing to the development of more robust and smarter fibrous artificial muscles.In the first section, we focus on the latest and most valuable progress on strengthening LCEF-based artificial muscles, highlighting the need for a comprehensive summary of the various approaches utilized. The mechanical properties of LCEFs can be tailored through molecular design, physical interactions, and fiber integration. The adjustment of hard/soft segment features, the introduction of additional microstructures, and the fiber integration provide opportunities to strengthen LCEF-based artificial muscles, which are discussed in the second section. Subsequently, we delve into the impact of various preparation methods on the performance of LCEFs, and LCEFs fabricated by different spinning and alignment techniques exhibited rather different mechanical and actuation properties. This has been adopted to engineer novel, stronger, and tailored fibrous artificial muscles, as described in the third section. Moreover, we show that the incorporation of rigid composite materials via coating and doping has emerged as a powerful strategy to strengthen LCEFs, such as core-shell structures. Such enhancements also introduce multifunctionality for LCE-based artificial muscles that can enrich the fiber structure and actuation mechanism, which are elucidated in the fourth section. Finally, we conclude this Account with a critical analysis of the challenges and prospects of LCE-based artificial muscles, hoping to pave the way for the construction of more powerful fibrous artificial muscles.