三乙胺
煅烧
八面体
热液循环
选择性
材料科学
纳米技术
纳米颗粒
化学工程
无机化学
化学
催化作用
有机化学
工程类
晶体结构
作者
Cheng Xu,Yi Shu,Tian Yuan Dong,Ji Ming Liu,Jin Sha Wei,Hong Jiang,Ping Ni,Ge Ge Fan,Jia Yun Guo
标识
DOI:10.1016/j.jece.2024.112515
摘要
Triethylamine (TEA) is typical hazardous volatile organic gas (VOCs), it is particularly important for us to effectively detect triethylamine in complex places. In this work, high efficiency triethylamine gas sensor based on SmVO4 was successfully obtained by means of hydrothermal reaction and assisted calcination. Characterization of analytical materials, SmVO4 octahedral nanoparticles formed clusters similar to pomegranate fruits. There is a trace +4 valence state of vanadium in the material, which contributes to the oxidation-reduction reaction between the target gas and the surface of the material. Gas sensitive test results found that the SmVO4 sensor still has a 2.45 response to the target gas (triethylamine) at low concentrations (1 ppm). SmVO4 shows excellent selectivity for triethylamine, with a response value more than three times that of other gases. In 25 days, it shows excellent stability and fast response recovery time (15 s/40 s). In addition, the gas sensing mechanism is analyzed.
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