化学
烷基
卤化物
有机化学
催化作用
组合化学
硼
作者
Wenhao Xu,Liejin Zhou,Tao Xu
出处
期刊:Synlett
[Georg Thieme Verlag KG]
日期:2023-01-16
卷期号:34 (10): 1075-1078
摘要
Abstract By merging nickel catalysis and photochemistry, we developed a deoxygenative alkylboration of aldehydes via a deoxygenative difunctionalization of carbonyls strategy. This three-component reaction between alkyl halides, B2Pin2, and aldehydes represents one of the most efficient methods to furnish the versatile secondary α,α-dialkyl boronates. A series of deoxygenative difunctionalization skeletons can be gained from the products based on the carbon–boron bond transformation. In addition, deoxygenative arylboration of aldehydes was achieved.
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