Adaptive Thermal Management Radiative Cooling Smart Window with Perfect Near‐Infrared Shielding

Abstract The architectural window with spectrally selective features and radiative cooling is an effective way to save building energy consumption. However, architectural windows that combine both functions are currently based on micro‐nano photonic structures, which undoubtedly hinder their commercial application due to the complexity of manufacture. Herein, a novel tunable visible light transmittance radiative cooling smart window (TTRC smart window) with perfect near‐infrared (NIR) shielding ability is manufactured via a mass‐producible scraping method. TTRC smart window presents high luminous transmittance ( T lum = 56.8%), perfect NIR shielding ( T NIR = 3.4%), bidirectional transparency adjustment ability unavailable in other transparent radiative coolers based on photonic structures (Δ T lum = 54.2%), and high emittance in the atmospheric window (over 94%). Outdoor measurements confirm that smart window can reduce 8.2 and 6.6 °C, respectively, compared to ordinary glass and indium tin oxide (ITO) glass. Moreover, TTRC smart window can save over 20% of annual energy in the tropics compared to ITO and ordinary glass. The simple preparation method employed in this work and the superior optical properties of the smart window have significantly broadened the scope of application of architectural windows and advanced the commercialization of architectural windows.