化学选择性
硼酸化
化学
催化作用
硼氢化
异构化
基质(水族馆)
钨
组合化学
选择性
有机化学
海洋学
地质学
烷基
芳基
作者
Tanner C. Jankins,Raúl Martín-Montero,Phillippa Cooper,Rubén Martı́n,Keary M. Engle
标识
DOI:10.33774/chemrxiv-2021-kn5xp
摘要
A tungsten-catalyzed hydroboration of unactivated alkenes at distal C(sp3)–H bonds aided by native directing groups is described herein. The method is characterized by its simplicity, exquisite regio- and chemoselectivity and wide substrate scope, offering a complementary site-selectivity pattern to other metal-catalyzed borylation reactions and chain-walking protocols.
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