化学
反应性(心理学)
吡那考
组合化学
曼尼希反应
范围(计算机科学)
有机化学
催化作用
计算机科学
医学
病理
程序设计语言
替代医学
作者
Stephen G. Pyne,Philip J. Chevis,Thanika Promchai,Christopher D. Richardson,Thunwadee Limtharakul
摘要
A highly diastereoselective method for the synthesis of syn-β-amino alcohols and enantioenriched anti-β-amino alcohols has been developed involving α-hydroxyl aldehydes and chiral α-phenylaminoxyaldehydes or α-benzoyloxyaldehydes, respectively in Petasis borono-Mannich allylation reactions. This study broadens the scope and utility of the Petasis reaction to include pinacol allylboronate and highlights its unique reactivity and stereochemical outcomes.
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