催化作用
水煤气变换反应
化学
材料科学
有机化学
作者
Siyu Yao,Xiao Zhang,Wu Zhou,Rui Gao,Wenqian Xu,Yifan Ye,Lili Lin,Xiaodong Wen,Ping Liu,Bingbing Chen,Ethan J. Crumlin,Jinghua Guo,Zhijun Zuo,Weizhen Li,Jinglin Xie,Li Lu,Christopher J. Kiely,Lin Gu,Chuan Shi,José A. Rodríguez
出处
期刊:Science
[American Association for the Advancement of Science (AAAS)]
日期:2017-07-27
卷期号:357 (6349): 389-393
被引量:704
标识
DOI:10.1126/science.aah4321
摘要
Low-temperature CO removal Carbon monoxide deactivates fuel cell catalysts, so it must be removed from H 2 generated from hydrocarbons on site. Yao et al. developed a catalyst composed of layered gold clusters on molybdenum carbide (MoC) nanoparticles to convert CO through its reaction with water into H 2 and CO 2 at temperatures as low as 150°C. Water was activated on MoC to form surface hydroxyl groups, which then reacted with CO adsorbed on the gold clusters. Science , this issue p. 389
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