普鲁士蓝
玻璃碳
介孔材料
傅里叶变换红外光谱
抗坏血酸
电催化剂
电化学
无机化学
电极
拉曼光谱
材料科学
化学
碳纤维
化学工程
核化学
循环伏安法
催化作用
有机化学
物理化学
物理
食品科学
光学
复合材料
复合数
工程类
作者
Jing Bai,Bin Qi,Jean Chrysostome Ndamanisha,Liping Guo
标识
DOI:10.1016/j.micromeso.2008.10.030
摘要
Ordered mesoporous carbon (OMC) was successfully modified with one kind of electroactive inorganic compounds: Prussian blue (PB). The composites were characterized by Fourier transform infrared spectroscopy (FT-IR), Raman spectroscopy, scanning electron microscopy (SEM) and electrochemical methods. The results show that, after depositing PB on the OMC, PB remains electroactivity. The new material obtained (PB/OMC) was used to modify glassy carbon electrode (GC). Compared with Prussian blue (PB) modified glassy carbon electrode (GC), the PB/OMC/GC electrode exhibits much better electrochemical stability, much wider pH range and larger response currents to the reduction of hydrogen peroxide (H2O2). Additionally, the PB/OMC/GC electrode also exhibits remarkably strong and stable electrocatalytic response toward the oxidation of ascorbic acid (AA) compared with PB/OMC.
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