Benign One‐Pot Synthesis of Carbamo(dithioperoxo)thioate Compounds in Water Medium Using N ‐(Arylthio)phthalimides as the Electrophilic Sulfur Source

Abstract Carbamo(dithioperoxo)thioate compounds have been synthesized in aqueous medium under open aerial condition at room temperature. N ‐(Arylthio)phthalimides are used as electrophilic sulfur donors which react with in situ generated dithiocarbamate anions to produce carbamo(dithioperoxo)thioates in excellent yields. After the reaction, phthalimide residue was recovered and reused to prepare N ‐(Arylthio)phthalimides.