化学
铜
傅里叶变换红外光谱
电化学气体传感器
胶体金
纳米复合材料
检出限
热重分析
核化学
扫描电子显微镜
光谱学
纳米颗粒
分析化学(期刊)
能量色散X射线光谱学
电化学
无机化学
作者
Saad A. Alkahtani,Ashraf M. Mahmoud,Mohamed M. El-Wekil
标识
DOI:10.1016/j.jelechem.2022.116102
摘要
• AuNPs@Cu-MOF was synthesized by a facile method. • It shows a good electro-catalytic activity towards D-PA determination. • D-PA is detected by the formation of complex at low potential. • The modified sensor shows wide linear range and low LOD. • The sensor was efficiently applied for capsules, plasma and urine samples. Copper based-metal organic frameworks modified with gold nanoparticles (AuNPs@Cu-MOF) was fabricated via facile approach. The nanocomposite was used to decorate glassy carbon electrode (GCE) for the electrochemical sensing of D- penicillamine (D-PA). The nanocomposite was characterized using different techniques such as scanning electron microscope (SEM), transmission electron microscope (TEM), energy dispersive X-ray spectroscopy (EDX), powder X-ray spectroscopy (PXRD), thermogravimetry (TGA), nitrogen adsorption–desorption isotherms, and Fourier Transform infrared spectroscopy (FTIR). Formation of a new anodic peak of Cu(II)-D-PA complex at + 0.38 V was used to detect D-PA. Cyclic and square wave voltammetric studies proved that AuNPs elevated the conductivity of Cu-MOF. The sensor exhibited wide linear range (0.4–75 × 10 −7 M) and low detection limit (0.11 × 10 −7 M) with a good sensitivity (0.9 ± 0.01 μA/μM). It was successfully applied for the estimation of D-PA in different real samples with recoveries % and relative standard deviations % (RSDs %) in the range of 95.6–102.5% and 2.4–3.3%, respectively.
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