Gradient Solid Electrolyte Interphase and Lithium‐Ion Solvation Regulated by Bisfluoroacetamide for Stable Lithium Metal Batteries

Abstract The structures and components of solid electrolyte interphase (SEI) are extremely important to influence the performance of full cells, which is determined by the formulation of electrolyte used. However, it is still challenging to control the formation of high‐quality SEI from structures to components. Herein, we designed bisfluoroacetamide (BFA) as the electrolyte additive for the construction of a gradient solid electrolyte interphase (SEI) structure that consists of a lithophilic surface with C−F bonds to uniformly capture Li ions and a LiF‐rich bottom layer to guide the rapid transportation of Li ions, endowing the homogeneous deposition of Li ions. Moreover, the BFA molecule changes the Li + solvation structure by reducing free solvents in electrolyte to improve the antioxidant properties of electrolyte and prevent the extensive degradation of electrolyte on the cathode surface, which can make a superior cathode electrolyte interphase (CEI) with high‐content LiF.