光催化
试剂
碘化物
催化作用
水溶液
化学
钙钛矿(结构)
化学工程
无机化学
材料科学
有机化学
工程类
作者
Rong Chen,Guodong Gao,Jingshan Luo
出处
期刊:Nano Research
[Springer Nature]
日期:2022-03-15
卷期号:15 (12): 10084-10089
被引量:4
标识
DOI:10.1007/s12274-022-4216-7
摘要
The utilization of perovskites as photocatalysts to convert CO2 into fuels and chemicals has received wide attention recently. However, their instability in water hinders their long-term application for overall photocatalytic CO2 reduction. Herein, we integrate the water-stable perovskite-like organolead iodide crystalline material [Pb8I8(H2O)3]8+[−O2C(CH2)4CO2−]4 (TJU-16) with Au co-catalyst for photocatalytic CO2 reduction in aqueous solution without sacrificial reagent. Under the AM 1.5 G simulated illumination, the TJU-16 with 0.19 wt.‰ Au co-catalyst steadily generated electrons for CO2 reduction reaction, which was 2.2 times of pure TJU-16. The Au0.19/TJU-16 catalyzed CO2 reduction at a rate of 84.2 µmol·g−1·h−1, and achieved a solar-to-fuel (STF) conversion efficiency of 0.034%. Our work will motivate the rational design of water-stable perovskite-like materials for photocatalytic applications.
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