低密度聚乙烯
结晶
超临界流体
结晶度
聚丙烯
挤压
聚乙烯
聚合物
聚合物结晶
材料科学
化学工程
反应挤出
线性低密度聚乙烯
高分子化学
复合材料
化学
有机化学
工程类
作者
Patrick Lee,Jin Wang,Chul B. Park
摘要
This paper presents an extrusion-based open-cell foaming process with polypropylene (PP)/polyethylene (PE) blends. The basic strategy for achieving a high open-cell content is to induce a hard/soft melt structure using two semicrystalline polymers with distinctively different crystallization temperatures (Tc) and to foam this inhomogeneous melt structure with supercritical CO2. The effects of polymer blending, die geometry, and temperature on cell opening were investigated in this study. Two blends of high-melt-strength (HMS) PP/metallocene PE (mPE) and linear PP/low-density PE (LDPE) were used as case examples.
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