An IR Study on Selective Hydrogenation of 1,3-Butadiene on Transition Metal Nitrides: 1,3-Butadiene and 1-Butene Adsorption on Mo2N/γ-Al2O3Catalyst

The surface species formed from the adsorption of 1,3-butadiene and 1-butene on Mo 2 N/γ-Al 2 O 3 catalyst have been characterized by in situ FT-IR spectroscopy with an attempt to get insight into the selective hydrogenation of 1,3-butadiene on transition metal nitride catalysts. 1,3-Butadiene adsorption on the Mo 2 N/γ-Al 2 O 3 catalyst forms several kinds of chemisorbed surface species: π-adsorbed butadiene (π s and π d ); σ-bonded species; dehydrogenated species. π s - and σ-bonded butene species are present on the surface for 1-butene adsorption and reaction on the nitride catalyst. The presence of the π d -adsorbed butadiene significantly prevents 1-butene from its adsorption, further hydrogenation, and isomerization on the nitrided catalyst, accordingly resulting in high selectivity in the hydrogenation of 1,3-butadiene to 1-butene. The surface nitrogen atoms weaken the interaction between 1,3-butadiene and the catalyst surface, and result in the high selectivity in the hydrogenation of 1,3-butadiene to 1-butene.