方铅矿
闪锌矿
吸附
X射线光电子能谱
傅里叶变换红外光谱
化学
核化学
朗缪尔吸附模型
接触角
无机化学
化学工程
材料科学
有机化学
矿物学
黄铁矿
复合材料
工程类
作者
Zhiyong Zhang,Wei Sun,Sheng Liu,Lu Zhang,Xiaoxue Niu,Mahmoud Mohamed Mohamed Ahmed,Guangyi Liu
标识
DOI:10.1016/j.molliq.2021.115902
摘要
In this paper, 5-amyl-1,2,4-triazole-3-thione (ATT) was firstly applied as a collector in flotation separation of galena (PbS) from sphalerite (ZnS). Micro-flotation results demonstrated that ATT selectively floated out galena from its mixture with sphalerite at pH ≤10.5. FTIR (Fourier transform infrared), adsorption capacity and contact angle indicated that to increase the pulp pH from ~6.2 to 10.0 dramatically reduced the adsorption of ATT on sphalerite, while had an insignificant effect on its adsorption towards galena. In situ AFM (atomic force microscopy) recommended a monolayer adsorption of ATT on galena surfaces at pH ~6.2 and 10.0. FTIR and XPS (X-ray photoelectron spectroscopy) gave out unequivocal evidences that ATT chemisorbed onto galena through combining surface Pb(II) with ATT's exo-S to generate PbS bond, which orientated ATT's amyl group outward for attaching bubbles, thus to realize the hydrophobization flotation of galena particles.
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