砜
膜
高分子化学
Nafion公司
磺酸
乙醚
材料科学
甲醇
芳烯
聚合物
质子交换膜燃料电池
芳基
电导率
化学
化学工程
复合材料
物理化学
有机化学
工程类
生物化学
电化学
烷基
电极
作者
Chang Liu,Xu Wang,Jingmei Xu,Chunmei Wang,Hao Chen,Wenchang Liu,Zhaoyu Chen,Xinming Du,Shuang Wang,Zhe Wang
标识
DOI:10.1016/j.ijhydene.2019.10.166
摘要
Sulfonated poly (aryl ether ketone sulfone) polymers (SPAEKS-PSA X) with the comb-shaped structure were prepared by grafting with 1, 3-propanesultone (PSA). The successful synthesis of SPAEKS-PSA X was confirmed by the FT-IR spectra. The morphology of the membrane was investigated by the small angle X-ray scattering and the transmission electron microscopy. The nanophase separation was brought in a comb-shaped structure between the main chains and the propyl sulfonic acid groups. The SPAEKS-PSA 15 membrane exhibited the highest conductivity of 101 mS cm−1 under 80 °C and 100% relative humidity conditions (100% RH). In addition, the methanol permeability coefficients of SPAEKS-PSA X membranes (7.56 × 10−7 to 9.44 × 10−7 cm2 s−1) were much lower compared to Nafion®117 (22.37 × 10−7 cm2 s−1). Meanwhile, the SPAEKS-PSA X membranes also displayed excellent mechanical properties (tensile modulus >30 MPa), thermal, oxidative stabilities and fuel cell performance. Considering the parameters above, especially the elevated proton conductivities as well as high methanol resistance, the comb-shaped structure is a promising design for DMFCs applications.
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