超级电容器
层状双氢氧化物
材料科学
阳极
电容
复合数
阴极
化学工程
热液循环
石墨烯
电极
水热合成
纳米技术
复合材料
化学
氢氧化物
物理化学
工程类
作者
Min Li,Ming Zhou,Wen Zhong,Jintao Zhang
标识
DOI:10.1016/j.est.2017.03.010
摘要
The flower-like NiFe layered double hydroxides loaded on Ni foam (NF/NiFe LDHs) are synthesized via one-pot hydrothermal method and the synthesized NF/NiFe LDHs are further coated with MnO2 nanosheets (MnO2@NF/NiFe LDHs) through an extra hydrothermal process. The excellent supercapacitor performance of MnO2@NF/NiFe LDH has been observed with a high capacitance of 4274.4 mF cm−2 at 5 mA cm−2 and a capacitance retention of 95.6% after 1000 cycles from a traditional three-electrode system. A low-cost flexible asymmetric supercapacitor has also been designed and fabricated using MnO2@NF/NiFe LDH as anode and active graphene as cathode. The working voltage window of this asymmetric supercapacitor is up to 1.4 V and the asymmetric supercapacitor delivered an energy density of 24.6 mWh cm−2 at 350 mW cm−2. These outstanding supercapacitor performances of the synthesized composite MnO2@NF/NiFe LDHs are attributed to the combination of unique NiFe layered double hydroxides structure and higher conductivity of MnO2 nanosheets.
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