Aramid Nanofiber‐Based Artificial Nacre‐Supported Graphene/Silver Nanowire Nanopapers for Electromagnetic Interference Shielding and Thermal Management

Abstract The development of next‐generation flexible electronics hinges on the creation of materials that are not only mechanically robust but also multifunctional. Herein, a novel approach is presented to fabricate an aramid nanofibers/cellulose nanocrystals/montmorillonite nanoplates (ACM) composite substrate with a robust “brick and mortar” microstructure. This substrate is seamlessly integrated with a high‐performance graphene/silver nanowire (G/Ag) composite conductive layer, resulting in the creation of ACM&G/Ag nanopapers. The resulting nanopapers achieve remarkable tensile strength (δ c ) (543.82 MPa), tensile modulus (E c ) (10.93 GPa), and toughness (U c ) (95.18 MJ m −3 ). Notably, when normalized by weight, the specific tensile strength of these nanopapers surpasses that of commercial titanium alloy, reaching 399.87 MPa g −1 cm 3 , compared to titanium alloy's 257.00 MPa g −1 cm 3 . With a high conductivity of 1398.08 S cm −1 , ACM&G/Ag nanopapers exhibit impressive electromagnetic interference shielding effectiveness (EMI SE) of 39.59 dB and EMI SE/t of 16359.26 dB cm −1 . Moreover, ACM&G/Ag nanopapers exhibit exceptional thermal management performance, featuring high electrical heating temperature (280 °C), rapid response time (<6 s), enduring heating stability, deicing capacity, and reliable heating performance even in humid environments. These results underscore the substantial potential of these high‐performance nanopapers in diverse applications such as wearable devices, electromagnetic compatibility, thermal management, human health, and aerospace.