Layered bimetallic hydroxide nanocage assembled on MnO2 nanotubes: A hierarchical porous sugar gourd-like electrocatalyst for the sensitive detection of hydrogen peroxide in food

Hydrogen peroxide is used widely as a disinfection or bleaching additive during processing in the food industry. However, excessive residues of hydrogen peroxide in food have serious human health implications. In the present study, a novel electrochemical sensing electrode (MnO2/ZIF-67@LDH) with hierarchical porous sugar gourd-like structure was fabricated through a multi-step hydrothermal method using ZIF as the precursor. The unique porous nanocage structure of the sensing electrode provided multidimensional charge transfer channels and accelerated the electron transfer rate. As a hydrogen peroxide sensor, the electrode had two detection linear ranges of 1×10-3-4 mmol L-1 and 4-8 mmol L-1, and the detection limit was 0.26 µmol L-1. The MnO2/ZIF-67@LDH sensor was also applied to determine the content of hydrogen peroxide in actual food samples of juice and milk, and satisfactory recovery were achieved. The present study provides a novel and effective design strategy for the construction of electrochemical sensing electrodes.