气凝胶
材料科学
极限氧指数
复合材料
热导率
保温
抗压强度
复合数
热稳定性
阻燃剂
化学工程
共晶体系
燃烧
化学
微观结构
有机化学
工程类
图层(电子)
烧焦
作者
Xiaohan Sun,Qianqian Yu,Fangmiao Wang,Senwei Hu,Jiazuo Zhou,Yifan Liu,Zishuai Jiang,Xin Wang,Yuan Yu,Haiyue Yang,Chengyu Wang
标识
DOI:10.1016/j.ijbiomac.2023.128599
摘要
High-performance biomass materials with good thermal insulation, flame retardrancy, and mechanical properties are urgently required for thermal management. Herein, a novel lignocellulose aerogel treated using a recyclable deep eutectic solvent (DES) was physically mixed with tourmaline particles (TPs) to enhance its structural stability, flame retardancy, and mechanical properties. The optimized TPs-modified lignocellulose aerogel (TLA-4) had good comprehensive performances due to the synergistic effect of ammonium sulfate and TPs. Compared with TPs-free lignocellulose aerogel (LA), the total heat release (THR) and heat release rate (HRR) of TLA-4 were reduced by 62.0 % and 66.3 %, respectively, and the limiting oxygen index (LOI) of TLA-4 was drastically enhanced by 74.1 %. TLA-4 also exhibited a low thermal conductivity of 29.67 mW/mK, showing favorable thermal insulation performance. When compressed to 5 %, the mechanical strength of TLA-4 increased by 8.3 times. Meanwhile, the presence of TPs and abundant pores in the aerogel contributed to the release of negative oxygen ions (NOIs), aiding air purification. A life cycle assessment (LCA) indicated that this composite had a minimal environmental impact (EI) in 17 categories compared to other similar aerogels. The proposed strategy for preparing an environment-friendly lignocellulose aerogel offers significant potential for applications in home decoration and building materials.
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