多硫化物
纤维素
纤维
纤维素纤维
锂(药物)
材料科学
电池(电)
纳米技术
硫黄
锂硫电池
化学
化学工程
有机化学
复合材料
电化学
工程类
电极
功率(物理)
物理化学
内分泌学
物理
医学
电解质
量子力学
作者
Yucheng Zhou,Ruoxi Chen,Jiajun He,Xiaodong Li
标识
DOI:10.1016/j.jpowsour.2023.233595
摘要
Decarbonization demands more batteries. Lithium-sulfur (Li–S) batteries are considered one of the most promising next-generation “post-Li-ion” batteries, whose practical viability is still hindered by two major challenges, polysulfide shuttling and dendritic lithium growth. Coating cellulose fibers onto separators has been proven to be an effective route for solving the two challenges simultaneously. Studying the working mechanism of the cellulose fiber is important yet difficult when the battery is in operation. Here, density functional theory and molecular dynamic simulations unveiled atomistically how cellulose fiber impedes polysulfides and lithium ions passing through the fiber, mitigating polysulfide shuttling and retarding dendritic lithium growth. This cost-effective modification paves the way towards more viable, sustainable Li–S batteries.
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