Synergistic strengthening of PVA ionic conductive hydrogels using aramid nanofibers and tannic acid for mechanically robust, antifreezing, water-retaining and antibacterial flexible sensors

Ion-conductive hydrogels with multi-functionality have gained significant attraction as flexible sensors in various fields such as wearable health monitoring and human motion detection, owing to their high ion conductivity, excellent flexibility and stretchability, and easy availability. In this work, multifunctional ion-conductive hydrogel with excellent mechanical properties, antifreezing properties, water retention and antibacterial performance was fabricated by the freeze-thaw crosslinking between polyvinyl alcohol (PVA) and aramid nanofibers (ANF), and the subsequent solution immersion crosslinking in a mixture of tannic acid (TA) and CaCl2 solution (DMSO/H2O as co-solvent). The rational engineering of a multi-spatial distributed hydrogen bond and Ca2+ coordination bond networks within the hydrogel led to a significant improvement in mechanical properties. Furthermore, through the introduction of TA and binary solvents (DMSO/H2O), the hydrogel had witnessed a substantial enhancement in its antimicrobial properties and water retention capacity. The resultant PAT5/CaCl2-5% (DMSO/H2O) hydrogel exhibited outstanding elongation at break (754.73%), tensile strength (6.25 MPa), electrical conductivity (3.09 S/m), which can be employed in flexible sensors to monitor real-time functional motion for human under diverse conditions. As such, this innovation opens up a novel pathway for envisioning flexible sensor devices, particularly in the realm of human activity monitoring.