The potential of multicylindrical dielectric barrier discharge plasma for diesel-contaminated soil remediation and biocompatibility assessment

This study explored the use of multicylindrical dielectric barrier discharge (MC-DBD) plasma technology to eliminate diesel fuel contamination from the soil. This study also assessed the environmental impact of plasma-generated reactive species on soil properties, plant growth, and the safety of microbial and human skin cells using various analytical methods. MC-DBD plasma was characterized using the current-voltage analysis and optical emission spectroscopy (OES). Gas Fourier transform infrared spectroscopy was employed to detect reactive species, such as O3, NO, NO2, N2O, and HNO3, in the plasma-treated air. The diesel fuel concentration in the soil was measured before and after plasma treatment using a gas chromatography-flame ionization detector. The efficacy of the MC-DBD plasma treatment was evaluated based on soil characteristics (pH and moisture), discharge parameters (power), and reactive species (O3 and NOx). Using only power of 30 W, the MC-DBD achieved a 94.19% removal of diesel fuel from the soil and yielded an energy efficiency of 1.78 × 10-2 m3/kWh within a 60-min treatment period. Neutral soil with a moisture content of 2% proved more effective in diesel fuel removal compared with acidic or alkaline soil with higher moisture content. O3 was the most efficient plasma-generated reactive species for diesel fuel removal and is involved in oxidation-induced fragmentation and volatilization. Overall, the potential of the MC-DBD plasma technology for remediating diesel fuel-contaminated soils is highlighted, and valuable insights for future applications are provided.