碳化
超级电容器
电容
材料科学
电化学
电极
化学工程
电流密度
功率密度
碳纤维
多孔性
小球藻
氮气
纳米技术
化学
复合材料
有机化学
复合数
植物
物理
工程类
物理化学
生物
功率(物理)
量子力学
藻类
扫描电子显微镜
作者
Chuan Yuan,Mao Chen,Kai Zhu,Jun Ni,Shuang Wang,Bin Cao,Shan Zhong,Jing Zhou,Shurong Wang
标识
DOI:10.1016/j.fuproc.2022.107466
摘要
Three-dimensionally (3D) nitrogen (N)-doped interconnected porous carbons (IPC) derived from cost-effective biomasses were facilely prepared by one-step method and utilized as electrochemical double layer capacitor (EDLC) electrodes. The reed and chlorella derived interconnected porous carbons (denoted as IPC-R and IPC-C) through carbonization with chemical activation both exhibited typical capacitive behaviors; importantly, by introducing N-rich chlorella into N-free reed by interactive‑carbonization, the resultant N-doped interconnected porous carbons (IPC-RC) positively demonstrated a high N content, a large specific surface area and pore volume as well as a high graphitization, which are crucial for fast ion diffusion and thus enhancing the electrochemical properties of supercapacitor. In the three-electrode system, the IPC-RC1.2 showed a superb specific capacitance of 340.4 F/g at a current density of 1 A/g, one of the highest capacitances for biomass derived‑carbon electrodes reported so far. Even at 20 A/g, the capacitance could achieve 265.5 F/g, revealing the superb rate capability. In the symmetric two-electrode system, the maximum power density and energy density reached up to 23.6 Wh/kg and 15,000 W/kg, respectively. Besides, an outstanding cycling stability was observed after 10,000 cycles.
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