过电位
电催化剂
分解水
材料科学
双功能
钴
析氧
氢氧化钴
阳极
阴极
氢氧化物
无机化学
化学工程
催化作用
镍
电极
化学
电化学
冶金
物理化学
有机化学
光催化
工程类
作者
Pravin Babar,A.C. Lokhande,Hyeong Ho Shin,B.S. Pawar,Myeng Gil Gang,S.M. Pawar,Jihun Kim
出处
期刊:Small
[Wiley]
日期:2017-12-18
卷期号:14 (7)
被引量:190
标识
DOI:10.1002/smll.201702568
摘要
Highly efficient and stable electrocatalysts from inexpensive and earth-abundant elements are emerging materials in the overall water splitting process. Herein, cobalt iron hydroxide nanosheets are directly deposited on nickel foam by a simple and rapid electrodeposition method. The cobalt iron hydroxide (CoFe/NF) nanosheets not only allow good exposure of the highly active surface area but also facilitate the mass and charge transport capability. As an anode, the CoFe/NF electrocatalyst displays excellent oxygen evolution reaction catalytic activity with an overpotential of 220 mV at a current density of 10 mA cm-2 . As a cathode, it exhibits good performance in the hydrogen evolution reaction with an overpotential of 110 mV, reaching a current density of 10 mA cm-2 . When CoFe/NF electrodes are used as the anode and the cathode for water splitting, a low cell voltage of 1.64 V at 10 mA cm-2 and excellent stability for 50 h are observed. The present work demonstrates a possible pathway to develop a highly active and durable substitute for noble metal electrocatalysts for overall water splitting.
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