材料科学
纳米复合材料
纤维素
氢键
细菌纤维素
微晶纤维素
化学工程
纳米晶
生物相容性
复合材料
聚酯纤维
复合数
盐酸
极限抗拉强度
高分子化学
有机化学
化学
纳米技术
分子
工程类
冶金
标识
DOI:10.1016/j.compscitech.2016.10.004
摘要
This work provides a direct evidence to investigate relationship between hydrogen bonding interactions and property enhancement of cellulose nanocrystals (CN) based bionanocomposites. Cellulose nanocrystal citrates (CNC) with more hydroxyl (OH) and carboxyl groups, CN and cellulose nanocrystal formates (CNF) with less OH groups were extracted from commercial microcrystalline cellulose using citric/hydrochloric acids, hydrochloric acid and formic/hydrochloric acids, respectively. Then different nanocrystals were incorporated into bacterial polyester poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) for tuning hydrogen bonding interactions and properties of PHBV nanocomposites. As expected, at the same loading contents, CNC had stronger reinforcing capability on PHBV matrix than CN and CNF. Compared to neat PHBV, tensile strengths of 10% CNF/PHBV, 10% CN/PHBV and 10% CNC/PHBV were improved by 146%, 166% and 187%, respectively. Especially, the maximum decomposition temperature of 10% CNC/PHBV was increased by 48.1 °C, and this nanocomposite showed superior barrier properties with a 64% reduction in water vapour permeability (WVP). Besides, the nanocomposites showed excellent biocompatibility to human MG-63 cells and lower overall migration levels. Such an outstanding reinforcement by CNC was ascribed to improved interfacial interaction (more hydrogen bonding interactions or hydrogen bond network), and nanodispersibility in the nanocomposites.
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