超级电容器
阴极
氧气
材料科学
电容
阳极
化学工程
碳纤维
功率密度
储能
纳米技术
电极
复合材料
功率(物理)
化学
电气工程
复合数
物理化学
工程类
物理
有机化学
量子力学
作者
Dongming Cai,Qinghe Cao,Junjie Du,Yang Liu,Fan Bu,Yi Yan,Xinhuan Lu,Qinghua Xia,Dan Zhou,Yuguo Xia
标识
DOI:10.1002/batt.202100344
摘要
Defect engineering such as oxygen vacancy in heterostructured electrode materials has emerged as a promising strategy to improve material performance in energy storage and conversion fields. The most common methods to introduce oxygen vacancies in energy materials usually involve high temperature treatment or strong reducing agents. In this work, we adopted a mild solvothermal treatment method to introduce oxygen vacancies into NiCo2O4 (Vo-NiCo2O4) nanoarrays. Owing to the increased oxygen vacancies and the improved surface area, the as-prepared Vo-NiCo2O4 on carbon cloth (Vo-NiCo2O4@CC) shows a high specific capacitance of 1389 mF cm−2 under the current density of 0.5 mA cm−2, and a remarkable capacitance retention of 93.8 % after 10000 cycles when used as cathode for supercapacitor. Moreover, an aqueous asymmetric supercapacitor was assembled using Vo-NiCo2O4@CC as cathode and AC@CC as anode and this device delivers a high energy density of 43.6 Wh kg−1 at a power density of 281 W kg−1. In addition, the as-assembled quasi-solid state asymmetric supercapacitor exhibits excellent mechanical flexibility and functions well while being bent at large angles or being twisted. This work offers a facile, cost-effective and practical available approach to finely tune the surface property of electrode materials towards flexible energy storage devices for wearable applications.
科研通智能强力驱动
Strongly Powered by AbleSci AI