膜
质子交换膜燃料电池
耐久性
Nafion公司
电解质
电导率
质子
材料科学
质子输运
磁导率
电化学能量转换
化学工程
纳米技术
复合材料
电化学
化学
电极
工程类
物理
生物化学
物理化学
量子力学
作者
Jing Sun,Dingbo Han,Mohamedazeem M. Mohideen,Shuzhen Li,Ce Wang,Ping Hu,Yong Liu
标识
DOI:10.1016/j.ijhydene.2023.10.342
摘要
Ion-conducting electrolyte membranes are essential parts of electrochemical energy storage devices like fuel cells and are crucial for energy conversion. However, the most widely used proton exchange membranes - Nafion, have problems such as strong dependence of conductivity on temperature and humidity, high cost and complex synthesis. So, researchers have been working to improve the comprehensive performance of membranes, including conductivity, stability, mechanical strength, and durability. To do this, the membrane structure must be maximized, which calls for applying the appropriate techniques to produce microstructure with excellent order, periodicity and connection. The development of vertical proton transport channels in the membrane will break through the limitation of raw materials and shorten the proton transport path. This will dramatically improve the proton conductivity in theory because protons are carried across membranes. Besides, different fillers and methods can also affect the fuel permeability, mechanical strength, and durability of the membrane. This research examines six technical approaches for building vertical channels around proton exchange membranes, including the nanofiber, electric field, magnetic field, template, heat treatment, and other approaches. The article summarizes relevant studies and practical uses, evaluates existing challenges and their remedies, and offers a projection of forthcoming progress.
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