化学
信号(编程语言)
光电化学
光电化学电池
纳米技术
电化学
电极
物理化学
材料科学
计算机科学
电解质
程序设计语言
作者
Yetong Ji,Xue Bai,Jing Tang,Bai Maosen,Zhu Yan-peng,Jianxin Tang
标识
DOI:10.1021/acs.analchem.3c05098
摘要
A self-powered photoelectrochemical (PEC) sensor has attracted widespread attention in the field of analysis, but it is still a challenge to enhance its response signals with rational strategies. In this work, a novel self-powered PEC sensing platform was developed for the quantitative detection of gatifloxacin (GAT) based on a photofuel cell consisting of two types of ZIF-derived ZnO/Co3O4 heterojunctions as photoactive materials. Peroxymonosulfate (PMS) was first used as an electron acceptor coupled with a photofuel cell to develop a synergetic signal amplification strategy. In a dual-photoelectrode system, the PMS activation on the ZnO@Co3O4 photocathode not only accelerated electron transfer from the Co3O4@ZnO photoanode to achieve strong signal intensity but also improved the sensing sensitivity by the oxidation reaction of generated highly active radicals to GAT. Compared with the absence of electron acceptors, the introduction of PMS produced a 2-fold enhancement in the signal output performance and a more than 72-fold improvement in the signal sensitivity. For the construction of the sensing interface, a molecularly imprinted polymer was assembled on the photocathode to specifically recognize GAT. The proposed sensor exhibited a detection range of 10–1 to 105 pM with a detection limit of 0.065 pM. The proposed sensing method has the advantages of sensitivity, simplicity, reliable stability, and anti-interference ability, which opens the door to the design of high-performance self-powered PEC sensors.
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