光谱学
铝
红外光谱学
热分析
金属
核磁共振波谱
脱水
衍射
元素分析
粉末衍射
固态
材料科学
化学
核化学
分析化学(期刊)
化学工程
结晶学
物理化学
无机化学
热的
有机化学
冶金
热力学
生物化学
量子力学
工程类
物理
光学
作者
Elsa Alvarez,Nathalie Guillou,Charlotte Martineau,Bart Bueken,Ben Van de Voorde,Clément Le Guillouzer,Paul Fabry,Farid Nouar,Françis Taulelle,Dirk De Vos,Jong‐San Chang,Kyoung Ho Cho,Naseem A. Ramsahye,Thomas Devic,Marco Daturi,Guillaume Maurin,Christian Serre
标识
DOI:10.1002/anie.201410459
摘要
Abstract The synthesis of the commercially available aluminum fumarate sample A520 has been optimized and its structure analyzed through a combination of powder diffraction, solid‐state NMR spectroscopy, molecular simulation, IR spectroscopy, and thermal analysis. A520 is an analogue of the MIL‐53(Al)‐BDC solid, but with a more rigid behavior. The differences between the commercial and the optimized samples in terms of defects have been investigated by in situ IR spectroscopy and correlated to their catalytic activity for ethanol dehydration.
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