Suppression of Initial Degradation via an Interfacial Charge-Induced Overshooting Effect in Solution-Processed Organic Light-Emitting Diodes

As the chemical stability of organic materials in organic light-emitting diodes (OLEDs) greatly impacts devices' lifetime, a thoughtful and advanced design of materials and device structures is necessary. In our work, we have achieved lifetime enhancement at its initial stage for solution-processed OLEDs. This improvement was realized through the implementation of a double electron transporting layer (dETL) composed of 2-[4-(9,10-dinaphthalen-2-yl-anthracen-2-yl)-phenyl]-1-phenyl-1H-benzoimidazole (ET) and hydroxyquinolinolato-lithium (Liq). A giant surface potential was generated at the surface of a constituent electron transport layer (ETL) that contained a higher concentration of Liq with high polarity. This giant surface potential simultaneously promoted the injection of trapped/accumulated electrons through the interface within dETL and the injection of holes from the anode, generating more exciton recombination events and ultimately enhancing efficiency by 133.0% and lifetime LT95 (luminance dropped by 5%) by 300% with an overshooting effect. Additionally, the degradation at the emitting layer was mitigated by shifting the degradation zone to the dETL, which was evidenced by laser desorption/ionization-time-of-flight (LDI-TOF) mass spectroscopy.