化学
催化作用
过氧化物
氧化磷酸化
碳纤维
硒
有机化学
开裂
组合化学
生物化学
材料科学
复合数
复合材料
作者
Xiaoxue Li,Hui‐Liang Hua,Yonghong Liu,Lei Yu
出处
期刊:Organic Letters
[American Chemical Society]
日期:2023-09-07
卷期号:25 (36): 6720-6724
被引量:3
标识
DOI:10.1021/acs.orglett.3c02569
摘要
Oxidative cracking of alkenes is a significant process in industry. In this work, it was found that catalyzed by Se/Fe via hybrid mechanisms, the carbon–carbon double bond in alkenes can break to produce carbonyls under mild conditions. Since O2 can be used as a partial oxidant, the employed H2O2 amount can be reduced (90 mol % vs 250 mol %) to avoid the peroxide residues, making the process even safer for operation.
科研通智能强力驱动
Strongly Powered by AbleSci AI