Advanced Liquid Metal-Based Hydrogels for Flexible Electronics

With the rapid development of flexible electronics in wearable devices, healthcare devices, and the Internet of Things (IoT), liquid metals (LMs)-based hydrogels have emerged as cutting-edge functional materials due to their high electrical conductivity, tunable mechanical properties, excellent biocompatibility, and unique self-healing properties. Through various physical or chemical methods, LMs can be integrated to form multifunctional LMs-based hydrogels, thus broadening the potential application fields. In this Review, the recent advancement in LMs-based hydrogels for flexible electronics is comprehensively and systematically reviewed from three aspects of synthesis methods, properties, and applications. For the first time, the existing innovative synthesis methods of LMs-based hydrogels are classified and summarized, including patterned LMs on/inside hydrogel substrates, LMs as conductive fillers in polymeric hydrogels, LMs as initiators in hydrogels, and LMs as cross-linkers with organic/inorganic materials. The synthesis mechanism is also stated in detail to highlight the multiple roles of LMs in adjusting the hydrogel properties. The versatile applications of LMs-based hydrogels in flexible electronics, including flexible sensors, wireless communications, electromagnetic interference (EMI) shielding, soft robot actuators, energy storage and conversion, etc., are separately described. Finally, the current challenges and future prospects of LMs-based hydrogels are proposed.