Mechanically Strong Nanocolloidal Supramolecular Plastics Assembled from Carbonized Polymer Dots with Photoactivated Room-Temperature Phosphorescence

The innovative development of supramolecular plastics (SPs) is recognized as one of the global efforts to address the environmental pollution caused by petroleum-based plastics. Traditional SPs usually show weak mechanical strength because of relatively weak noncovalent bonds and a lack of appropriate functions for practical applications. To overcome these limitations, we herein report nanocolloidal supramolecular plastics (NSPs) assembled from newly emerging nanoparticles, namely, carbonized polymer dots (CPDs) modified with ureido pyrimidinone groups. These NSPs display good mechanical properties, unique photoactivated room-temperature phosphorescence (RTP), and excellent solvent stability. Notably, NSPs are recyclable with maintenance of their original mechanics and photoactivated RTP after several usages. Furthermore, photoactivated RTP with multiple colors is achieved by incorporating organic molecules into NSPs. We show proof-of-concept applications of NSPs in high-level information security. The results in this work pave an avenue toward functional materials assembled from CPDs and will advance the development of innovative nanomaterials for sustainable applications.