Copper‐Catalyzed Intermolecular Aminocyanation and Diamination of Alkenes

'N' front and center: The facile construction of C-N bonds by the generation of nitrogen-centred radicals from N-fluorobenzenesulfonimide results in the aminative difuctionalization of alkenes. The first copper-catalyzed intermolecular aminocyanation of alkenes and diamination of styrenes were realized. Si-F and B-F interactions play a significant role in the reaction.