Synergistic effect between Er‐doped MoS 2 nanosheets and interfacial Mo–N coupling phases for enhanced electrocatalytic hydrogen evolution

Hydrogen production via electrochemical water splitting is a promising and green technology. As one of the most representative transition metal sulfides layered materials, Molybdenum disulfide (MoS 2 ) has immense potential for the hydrogen evolution reaction (HER). We successfully prepared a nitrogen‐doped carbon (NC) in situ‐grown erbium‐doped MoS 2 polyhedral structure (Er‐MoS 2 /NC) that incorporates an interfacial Mo–N coupling phase. The Er‐MoS 2 /NC catalyst possesses superior HER catalytic activity with a overpotential of 5 mV at the current density of 10 mA·cm ‐2 and a small Tafel slope about 76 mV·dec‐1 along with excellent stability. The synergistic effect of rare‐earth doping and the interfacial Mo–N coupling phase effectively modifies the electronic structure of layered MoS 2 by increasing the exposed active sites and further lowering the hydrogen adsorption energy. The present work offers a new avenue for synthesizing multilayer nanostructured materials to improve the performance of sulfide‐based materials for electrocatalytic HER.