Flame-retardant poly(L-lactic acid) with enhanced UV protection and well-preserved mechanical properties by a furan-containing polyphosphoramide

Despite good biodegradability and mechanical strength, the intrinsic flammability of poly(L-lactic acid) (PLA) impede its practical application. Introducing phosphoramide is an effective method to enhance the flame retardancy of PLA. However, most of the reported phosphoramides derive from petroleum resources, and their addition tends to deteriorate the mechanical properties, especially toughness, of PLA. Herein, a bio-based, furan-containing polyphosphoramide (DFDP) with high flame-retardant efficiency was synthesized for PLA. Our study found that 2 wt% DFDP enabled PLA to pass a UL-94 V-0 rating, and 4 wt% DFDP increased the limiting oxygen index (LOI) to 30.8 %. DFDP effectively maintained the mechanical strength and toughness of PLA. The tensile strength of PLA with 2 wt% DFDP reached 59.9 MPa, and its elongation at break and impact strength were increased by 15.8 % and 34.3 %, respectively, relative to those of virgin PLA. The UV protection of PLA was significantly enhanced by introducing DFDP. Hence, this work provides a sustainable and comprehensive strategy for the creation of flame-retardant biomaterials with improved UV protection and well-preserved mechanical properties, which possess a broad prospect in industrial application.