Electrophilic-Attack Doped Organic Field-Effect Transistors for Ultrasensitive and Selective Hydrogen Sulfide Detection

Doping of organic semiconductors (OSCs) has been developed as an effective means of modulating the density and transfer efficiency of charge carriers; however, realization of effective doping to tailor the chemical sensing performance of OSC-based sensors still remains not explored extensively. In addition, the application of OSCs in chemical sensors is usually limited by the poor stability and low selectivity. Herein, flexible donor-acceptor copolymer-based organic field-effect transistor (OFET) chemical sensors are designed via an electrophilic attack doping strategy. The p-dopant trityl tetrakis(pentafluorophenyl) borate (TrTPFB) can be effectively doped into the host molecular