阳极
材料科学
电化学
电解质
锂(药物)
化学工程
碳纤维
纳米颗粒
复合数
纳米技术
电极
化学
复合材料
医学
物理化学
内分泌学
工程类
作者
Qichang Pan,Fenghua Zheng,Xing Ou,Chenghao Yang,Xunhui Xiong,Zhenghua Tang,Lingzhi Zhao,Meilin Liu
出处
期刊:ACS Sustainable Chemistry & Engineering
[American Chemical Society]
日期:2017-04-26
卷期号:5 (6): 4739-4745
被引量:67
标识
DOI:10.1021/acssuschemeng.7b00119
摘要
Fe3O4/Fe1–xS@C@MoS2 nanosheets consisting of Fe3O4/Fe1–xS nanoparticles embedded in carbon nanosheets and coated by MoS2 were synthesized via a facile and scalable strategy with assistance of NaCl template. With Fe3O4/Fe1–xS@C@MoS2 nanosheets composite as an anode for LIBs and SIBs, the Fe3O4/Fe1–xS@C@MoS2 nanosheets composite shows outstanding electrochemical performance because of the synergistic effects of the Fe3O4/Fe1–xS nanoparticles, carbon nanosheets and MoS2. In this unique constructed architecture, on one hand, the carbon nanosheets can avoid the direct exposure of Fe3O4/Fe1–xSNPs to the electrolyte; on the other hand, the carbon nanosheets can buffer the volume change of Fe3O4/Fe1–xS NPs as well as suppress the aggregation of Fe3O4/Fe1–xS NPs during the cycling processes. Moreover, MoS2 can offer high interfacial contact areas between active materials/electrolyte, resulting in rapid charge transfer and higher capacity. As a consequence, Fe3O4/Fe1–xS@C@MoS2 nanosheets exhibit high reversible capacity of 1142 mAhg–1 after 700 cycles at 1.0 A g–1 and 640 mA h g–1 at 5.0 A g–1for LIBs, 402 mA h g–1 after 1000 cycles at 1.0 A g–1and 355 mA h g–1 at 2.0 A g–1 for SIBs, respectively. This outstanding electrochemical performance indicated that the Fe3O4/Fe1–xS@C@MoS2 nanosheets have potential as anode for high-performance LIBs and SIBs.
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